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פותח על ידי קלירמאש פתרונות בע"מ -
Diastereoselective hydrogenations of unsymmetrically substituted aromatics
Year:
1995
Source of publication :
Chirality
Authors :
הניג, הלמוט
;
.
Volume :
7
Co-Authors:
Exl, C., Institute of Organic Chemistry, Graz University of Technology, Graz, Austria
Ferstl, E., Institute of Organic Chemistry, Graz University of Technology, Graz, Austria
Hönig, H., Institute of Organic Chemistry, Graz University of Technology, Graz, Austria
Rogi‐Kohlenprath, R., Institute of Organic Chemistry, Graz University of Technology, Graz, Austria
Facilitators :
From page:
211
To page:
218
(
Total pages:
8
)
Abstract:
Attempts to induce enantioselectivity in the catalytic hydrogenation of unsymmetrically substituted aromatics using covalently bound, well known chiral auxiliaries are described. Marked differences in stereoselectivity and rate of hydrogenolysis are noted as a function of the auxiliary used. Enantioselectivities obtained in the resulting cyclohexyl derivatives are rather poor. © 1995 Wiley‐Liss, Inc. Copyright © 1995 Wiley‐Liss, Inc.
Note:
Related Files :
aromatic compound
benzoic acid derivative
Chirality
Conference paper
L‐proline
organic chemistry
עוד תגיות
תוכן קשור
More details
DOI :
10.1002/chir.530070406
Article number:
Affiliations:
Database:
סקופוס
Publication Type:
מאמר
;
.
Language:
אנגלית
Editors' remarks:
ID:
20238
Last updated date:
02/03/2022 17:27
Creation date:
16/04/2018 23:35
Scientific Publication
Diastereoselective hydrogenations of unsymmetrically substituted aromatics
7
Exl, C., Institute of Organic Chemistry, Graz University of Technology, Graz, Austria
Ferstl, E., Institute of Organic Chemistry, Graz University of Technology, Graz, Austria
Hönig, H., Institute of Organic Chemistry, Graz University of Technology, Graz, Austria
Rogi‐Kohlenprath, R., Institute of Organic Chemistry, Graz University of Technology, Graz, Austria
Diastereoselective hydrogenations of unsymmetrically substituted aromatics
Attempts to induce enantioselectivity in the catalytic hydrogenation of unsymmetrically substituted aromatics using covalently bound, well known chiral auxiliaries are described. Marked differences in stereoselectivity and rate of hydrogenolysis are noted as a function of the auxiliary used. Enantioselectivities obtained in the resulting cyclohexyl derivatives are rather poor. © 1995 Wiley‐Liss, Inc. Copyright © 1995 Wiley‐Liss, Inc.
Scientific Publication
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