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פותח על ידי קלירמאש פתרונות בע"מ -
Does arachidonic acid exist in a well defined tertiary structure ?
Year:
1989
Source of publication :
Journal of Molecular Liquids
Authors :
הניג, הלמוט
;
.
Volume :
40
Co-Authors:
Sterk, H., Institute of organic chemistry Karl Franzens Universität Graz, Austria
Konrat, R., Institute of organic chemistry Karl Franzens Universität Graz, Austria
Hönig, H., Institute of organic chemistry Technische Universität Graz, Austria
Facilitators :
From page:
101
To page:
115
(
Total pages:
15
)
Abstract:
2d n.O.e. experiments as well as 1H and 13C relaxation time measurements force one to assume that arachidonic acid in solution exists at least partially in a backfolded tightly packed structure. Thereby in CDCl3 this packed structure is most favored, whereas in CD3OD it seems to be of no valuable importance. Force field calculations performed on the same subject end up with four minima on the potential energy surface. One of those minima is well suited to explain the nmr results solely on basis of the r-6 dependence of intramolecular dipolar relaxation. © 1989.
Note:
Related Files :
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More details
DOI :
10.1016/0167-7322(89)80039-X
Article number:
Affiliations:
Database:
סקופוס
Publication Type:
מאמר
;
.
Language:
אנגלית
Editors' remarks:
ID:
20388
Last updated date:
02/03/2022 17:27
Creation date:
16/04/2018 23:36
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Scientific Publication
Does arachidonic acid exist in a well defined tertiary structure ?
40
Sterk, H., Institute of organic chemistry Karl Franzens Universität Graz, Austria
Konrat, R., Institute of organic chemistry Karl Franzens Universität Graz, Austria
Hönig, H., Institute of organic chemistry Technische Universität Graz, Austria
Does arachidonic acid exist in a well defined tertiary structure ?
2d n.O.e. experiments as well as 1H and 13C relaxation time measurements force one to assume that arachidonic acid in solution exists at least partially in a backfolded tightly packed structure. Thereby in CDCl3 this packed structure is most favored, whereas in CD3OD it seems to be of no valuable importance. Force field calculations performed on the same subject end up with four minima on the potential energy surface. One of those minima is well suited to explain the nmr results solely on basis of the r-6 dependence of intramolecular dipolar relaxation. © 1989.
Scientific Publication
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