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אסיף מאגר המחקר החקלאי
פותח על ידי קלירמאש פתרונות בע"מ -
Organic sorbate-organoclay interactions in aqueous and hydrophobic environments: Sorbate-water competition
Year:
2008
Authors :
בוריסובר, מיכאל
;
.
גרסטל, זאב
;
.
מינגלגרין, אורי
;
.
Volume :
42
Co-Authors:
Borisover, M., Institute of Soil, Water and Environmental Sciences, Volcani Center, Agricultural Research Organization, Bet Dagan, 50250, Israel
Gerstl, Z., Institute of Soil, Water and Environmental Sciences, Volcani Center, Agricultural Research Organization, Bet Dagan, 50250, Israel
Burshtein, F., Department of Inorganic and Analytical Chemistry, Hebrew University of Jerusalem, Jerusalem 91904, Israel
Yariv, S., Department of Inorganic and Analytical Chemistry, Hebrew University of Jerusalem, Jerusalem 91904, Israel
Mingelgrin, U., Institute of Soil, Water and Environmental Sciences, Volcani Center, Agricultural Research Organization, Bet Dagan, 50250, Israel
Facilitators :
From page:
7201
To page:
7206
(
Total pages:
6
)
Abstract:
Sorption of nitrobenzene, phenol, and m-nitrophenol from water and n-hexadecane was measured on Na-montmorillonite and organoclays in which 41 and 90% of the exchange capacity of the Na-clay was occupied by hexadecyltrimethylammonium. The strength of sorbate-sorbent interactions in n-hexadecane for all three sorbents was in the following order: nitrobenzene < phenol < m-nitrophenol. The magnitude of the distribution coefficients suggests that the contribution to solute uptake of partitioning between n-hexadecane and the organic pseudophase of the dried organoclays is minor, whereas the major contribution is from adsorptive sorbate-sorbent interactions. Sorption isotherms obtained in different solvents were compared using a sorbate activity scale. In the organoclays, the stronger the tendency of a sorbate to interact with sorption sites, the less pronounced is the reduction in the activity-based sorption due to competition with water. The order of this reduction for the different sorbates is nitrobenzene > phenol > m-nitrophenol. The weakening of sorbate-sorbent interactions resulting from water-sorbate competition might be mitigated by interaction between the organic sorbate and sorbed water molecules. Since the more strongly interacting organic compounds are less susceptible to suppression of sorption in the presence of water, hydrating organoclays may result in an increased differentiation between "weakly" and "strongly" interacting ("nonpolar" and "polar") compounds in the organoclay phase. © 2008 American Chemical Society.
Note:
Related Files :
Adsorption
Clay minerals
Distribution coefficients
Na-montmorillonite
organic pollution
phenol
phenols
water
עוד תגיות
תוכן קשור
More details
DOI :
10.1021/es801116b
Article number:
0
Affiliations:
Database:
סקופוס
Publication Type:
מאמר
;
.
Language:
אנגלית
Editors' remarks:
ID:
26615
Last updated date:
02/03/2022 17:27
Creation date:
17/04/2018 00:24
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Scientific Publication
Organic sorbate-organoclay interactions in aqueous and hydrophobic environments: Sorbate-water competition
42
Borisover, M., Institute of Soil, Water and Environmental Sciences, Volcani Center, Agricultural Research Organization, Bet Dagan, 50250, Israel
Gerstl, Z., Institute of Soil, Water and Environmental Sciences, Volcani Center, Agricultural Research Organization, Bet Dagan, 50250, Israel
Burshtein, F., Department of Inorganic and Analytical Chemistry, Hebrew University of Jerusalem, Jerusalem 91904, Israel
Yariv, S., Department of Inorganic and Analytical Chemistry, Hebrew University of Jerusalem, Jerusalem 91904, Israel
Mingelgrin, U., Institute of Soil, Water and Environmental Sciences, Volcani Center, Agricultural Research Organization, Bet Dagan, 50250, Israel
Organic sorbate-organoclay interactions in aqueous and hydrophobic environments: Sorbate-water competition
Sorption of nitrobenzene, phenol, and m-nitrophenol from water and n-hexadecane was measured on Na-montmorillonite and organoclays in which 41 and 90% of the exchange capacity of the Na-clay was occupied by hexadecyltrimethylammonium. The strength of sorbate-sorbent interactions in n-hexadecane for all three sorbents was in the following order: nitrobenzene < phenol < m-nitrophenol. The magnitude of the distribution coefficients suggests that the contribution to solute uptake of partitioning between n-hexadecane and the organic pseudophase of the dried organoclays is minor, whereas the major contribution is from adsorptive sorbate-sorbent interactions. Sorption isotherms obtained in different solvents were compared using a sorbate activity scale. In the organoclays, the stronger the tendency of a sorbate to interact with sorption sites, the less pronounced is the reduction in the activity-based sorption due to competition with water. The order of this reduction for the different sorbates is nitrobenzene > phenol > m-nitrophenol. The weakening of sorbate-sorbent interactions resulting from water-sorbate competition might be mitigated by interaction between the organic sorbate and sorbed water molecules. Since the more strongly interacting organic compounds are less susceptible to suppression of sorption in the presence of water, hydrating organoclays may result in an increased differentiation between "weakly" and "strongly" interacting ("nonpolar" and "polar") compounds in the organoclay phase. © 2008 American Chemical Society.
Scientific Publication
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