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 Fidel, R.B., Thompson, M.L. and Laird, D.A.,

The Boehm titration was developed to characterise acidic functionalities on carbon black
and activated carbon surfaces (Boehm et al. 1964). The method is based on the principle
that acidic surface groups differ in the strength of their acidity and hence can be titrated by
bases of different strengths. The original Boehm method divides acidic functional groups on
activated carbon or carbon black surfaces into three pKa ranges:~ 5.0–6.4, 6.4–10.3 and
10.3–13.0 (Boehm et al. 1964). Functional groups within these pKa ranges include, but are …

Chapter 8

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Determining acidic groups at biochar surfaces via the Boehm titration

 Fidel, R.B., Thompson, M.L. and Laird, D.A.,

Determining acidic groups at biochar surfaces via the Boehm titration

The Boehm titration was developed to characterise acidic functionalities on carbon black
and activated carbon surfaces (Boehm et al. 1964). The method is based on the principle
that acidic surface groups differ in the strength of their acidity and hence can be titrated by
bases of different strengths. The original Boehm method divides acidic functional groups on
activated carbon or carbon black surfaces into three pKa ranges:~ 5.0–6.4, 6.4–10.3 and
10.3–13.0 (Boehm et al. 1964). Functional groups within these pKa ranges include, but are …

Chapter 8

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