Reducing nitrate leaching from agricultural land to aquifers is a high priority concern for more than a half a century. This study presents theory and observations of a threshold concentration of nitrate in the root zone (Cmax), which the leachate concentration increases at higher rates with increasing root-zone nitrate concentration. Cmax is derived both by direct results from container experiments with varying nitrogen (N) fertigation, and as a calibration parameter in N-transport models beneath commercial agricultural plots. For 5 different crops, Cmax ranged between 20-45 mg/l of NO3 -N derived from experiments and models. However, for lettuce, which was irrigated with a large leaching fraction, Cmax could not be defined. In crops irrigated and fertilized in the warm/dry season (corn and citrus), the experiments show a dramatic change in leachate-concentration slope, and simulations reveal a wide range of sensitivity of leachate NO3 -N concentration to Cmax. In annual crops irrigated and fertilized in the cool/wet season (e.g., potato in a Mediterranean climate), the experiments show a distinct Cmax that is less dramatic than that of the summer-irrigated crops in the container experiment, and smaller impact of Cmax in N-transport models. The simulations show that, for summer-irrigated crops, maintaining fertigation at C < Cmax has a significant effect reducing deep leachate concentrations, whereas for the winter annual crops the simulations revealed no threshold effect. It is suggested that for summer-irrigated crops, fertigation below Cmax robustly serves the co-sustainability of intensive agriculture and aquifer water quality; this is also suggested for winter crops, but benefits are not robust. For short season, small root-system crops (e.g., lettuce), efforts should be made to detach the crop from the soil.
Reducing nitrate leaching from agricultural land to aquifers is a high priority concern for more than a half a century. This study presents theory and observations of a threshold concentration of nitrate in the root zone (Cmax), which the leachate concentration increases at higher rates with increasing root-zone nitrate concentration. Cmax is derived both by direct results from container experiments with varying nitrogen (N) fertigation, and as a calibration parameter in N-transport models beneath commercial agricultural plots. For 5 different crops, Cmax ranged between 20-45 mg/l of NO3 -N derived from experiments and models. However, for lettuce, which was irrigated with a large leaching fraction, Cmax could not be defined. In crops irrigated and fertilized in the warm/dry season (corn and citrus), the experiments show a dramatic change in leachate-concentration slope, and simulations reveal a wide range of sensitivity of leachate NO3 -N concentration to Cmax. In annual crops irrigated and fertilized in the cool/wet season (e.g., potato in a Mediterranean climate), the experiments show a distinct Cmax that is less dramatic than that of the summer-irrigated crops in the container experiment, and smaller impact of Cmax in N-transport models. The simulations show that, for summer-irrigated crops, maintaining fertigation at C < Cmax has a significant effect reducing deep leachate concentrations, whereas for the winter annual crops the simulations revealed no threshold effect. It is suggested that for summer-irrigated crops, fertigation below Cmax robustly serves the co-sustainability of intensive agriculture and aquifer water quality; this is also suggested for winter crops, but benefits are not robust. For short season, small root-system crops (e.g., lettuce), efforts should be made to detach the crop from the soil.