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Hydrogen bonds formed by methyl groups of acetonitrile: Infrared and calorimetric study
Year:
1994
Authors :
Borisover, Mikhail
;
.
Volume :
50
Co-Authors:
Stolov, A.A., Kazan State University, Lenin Street 18, Kazan, 420008, Russian Federation
Kamalova, D.I., Kazan State University, Lenin Street 18, Kazan, 420008, Russian Federation
Borisover, M.D., Kazan State University, Lenin Street 18, Kazan, 420008, Russian Federation
Solomonov, B.N., Kazan State University, Lenin Street 18, Kazan, 420008, Russian Federation
Remizov, A.B., Kazan Chemistry Technology Institute, Karl Marx Street 68, Kazan, 420015, Russian Federation
Facilitators :
From page:
145
To page:
150
(
Total pages:
6
)
Abstract:
Solutions of acetonitrile (I) in tetrachloromethane and deuteratred solvents (S) (benzene, acctonitrile, acetone and dimethylsulphoxide) have been studied by IR absorption spectra. The observed solvent effect on the IR spectrum of I was explained in terms of the existence of complexes with hydrogen bonding of the type NCCH3...solvent (S). The strength of the hydrogen bonding was characterized by enthalpies of specific interactions of I with solvents ΔHI/S int(sp). The values ΔHI/S int(sp) were determined both by IR spectroscopy and calorimetry and were found to be within the range 0.3-1.5 kcal mol-1. © 1993.
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DOI :
10.1016/0584-8539(94)80122-3
Article number:
0
Affiliations:
Database:
Scopus
Publication Type:
article
;
.
Language:
English
Editors' remarks:
ID:
21795
Last updated date:
02/03/2022 17:27
Creation date:
16/04/2018 23:46
Scientific Publication
Hydrogen bonds formed by methyl groups of acetonitrile: Infrared and calorimetric study
50
Stolov, A.A., Kazan State University, Lenin Street 18, Kazan, 420008, Russian Federation
Kamalova, D.I., Kazan State University, Lenin Street 18, Kazan, 420008, Russian Federation
Borisover, M.D., Kazan State University, Lenin Street 18, Kazan, 420008, Russian Federation
Solomonov, B.N., Kazan State University, Lenin Street 18, Kazan, 420008, Russian Federation
Remizov, A.B., Kazan Chemistry Technology Institute, Karl Marx Street 68, Kazan, 420015, Russian Federation
Hydrogen bonds formed by methyl groups of acetonitrile: Infrared and calorimetric study
Solutions of acetonitrile (I) in tetrachloromethane and deuteratred solvents (S) (benzene, acctonitrile, acetone and dimethylsulphoxide) have been studied by IR absorption spectra. The observed solvent effect on the IR spectrum of I was explained in terms of the existence of complexes with hydrogen bonding of the type NCCH3...solvent (S). The strength of the hydrogen bonding was characterized by enthalpies of specific interactions of I with solvents ΔHI/S int(sp). The values ΔHI/S int(sp) were determined both by IR spectroscopy and calorimetry and were found to be within the range 0.3-1.5 kcal mol-1. © 1993.
Scientific Publication
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