Advanced Search
Journal of Organic Chemistry
Dunkelblum, E., Department of Chemistry, Michigan State University, East Lansing, MI 48824, United States
Hart, H., Department of Chemistry, Michigan State University, East Lansing, MI 48824, United States
The reaction of several polymethylnaphthalenes with excess n-BuLi-TMEDA in THF-hexane resulted mainly in monometalation of a methyl substituent. In contrast with what might be expected from simple molecular orbital calculations, metalation of a C 2 methyl group was preferred over that of a C 1 methyl group. © 1979 American Chemical Society.
Powered by ClearMash Solutions Ltd -
Volcani treasures
About
Terms of use
Metalation of polymethylnaphthalenes
44
Dunkelblum, E., Department of Chemistry, Michigan State University, East Lansing, MI 48824, United States
Hart, H., Department of Chemistry, Michigan State University, East Lansing, MI 48824, United States
Metalation of polymethylnaphthalenes
The reaction of several polymethylnaphthalenes with excess n-BuLi-TMEDA in THF-hexane resulted mainly in monometalation of a methyl substituent. In contrast with what might be expected from simple molecular orbital calculations, metalation of a C 2 methyl group was preferred over that of a C 1 methyl group. © 1979 American Chemical Society.
Scientific Publication
You may also be interested in