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Weissenberg, M., Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, Israel
Glotter, E., Faculty of Agriculture, Hebrew University of Jerusalem, P.O. Box 12, Rehovot 76-100, Israel
The formation of cis- and trans-epoxy-alcohols by treatment of steroidal epoxy-ketones with sodium borohydride is analysed in terms of the direction of attack on the corresponding unsubstituted ketones, and the steric hindrance exerted by the epoxide ring.
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Steric course of reduction with sodium borohydride of steroidal αβepoxy-ketones
Weissenberg, M., Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, Israel
Glotter, E., Faculty of Agriculture, Hebrew University of Jerusalem, P.O. Box 12, Rehovot 76-100, Israel
Steric course of reduction with sodium borohydride of steroidal αβepoxy-ketones
The formation of cis- and trans-epoxy-alcohols by treatment of steroidal epoxy-ketones with sodium borohydride is analysed in terms of the direction of attack on the corresponding unsubstituted ketones, and the steric hindrance exerted by the epoxide ring.
Scientific Publication
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