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Steric course of reduction with sodium borohydride of steroidal αβepoxy-ketones
Year:
1978
Authors :
Weissenberg, Martin
;
.
Volume :
Co-Authors:
Weissenberg, M., Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, Israel
Glotter, E., Faculty of Agriculture, Hebrew University of Jerusalem, P.O. Box 12, Rehovot 76-100, Israel
Facilitators :
From page:
568
To page:
571
(
Total pages:
4
)
Abstract:
The formation of cis- and trans-epoxy-alcohols by treatment of steroidal epoxy-ketones with sodium borohydride is analysed in terms of the direction of attack on the corresponding unsubstituted ketones, and the steric hindrance exerted by the epoxide ring.
Note:
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DOI :
Article number:
Affiliations:
Database:
Scopus
Publication Type:
article
;
.
Language:
English
Editors' remarks:
ID:
24579
Last updated date:
02/03/2022 17:27
Creation date:
17/04/2018 00:08
Scientific Publication
Steric course of reduction with sodium borohydride of steroidal αβepoxy-ketones
Weissenberg, M., Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, Israel
Glotter, E., Faculty of Agriculture, Hebrew University of Jerusalem, P.O. Box 12, Rehovot 76-100, Israel
Steric course of reduction with sodium borohydride of steroidal αβepoxy-ketones
The formation of cis- and trans-epoxy-alcohols by treatment of steroidal epoxy-ketones with sodium borohydride is analysed in terms of the direction of attack on the corresponding unsubstituted ketones, and the steric hindrance exerted by the epoxide ring.
Scientific Publication
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