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Poverenov, E., Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, 76100, Israel
Milstein, D., Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, 76100, Israel
A new reaction of haloalkylzinc compounds, leading to transition metal carbenes, is described; halomethylzinc and halobenzylzinc compounds react with ruthenium and iridium complexes to form methylene and benzylidene complexes, including the Grubbs catalyst. © The Royal Society of Chemistry.
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Formation of transition metal carbenes using haloalkylzinc reagents
Poverenov, E., Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, 76100, Israel
Milstein, D., Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, 76100, Israel
Formation of transition metal carbenes using haloalkylzinc reagents
A new reaction of haloalkylzinc compounds, leading to transition metal carbenes, is described; halomethylzinc and halobenzylzinc compounds react with ruthenium and iridium complexes to form methylene and benzylidene complexes, including the Grubbs catalyst. © The Royal Society of Chemistry.
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