אסיף מאגר המחקר החקלאי

Synthesis in Jasmone Series. IV. Preparation of Methyl‐2‐Oxo‐5‐Pentylcyclopentyl‐1‐Acetate and its 4‐Pentyl Analogue

Year:

1975

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Volume :

13

Co-Authors:

Ravid, U., Department of Organic Chemistry, Natural Products Laboratory, Hebrew University of Jerusalem, Jerusalem, 91000, Israel
Hoffer, D., Department of Organic Chemistry, Natural Products Laboratory, Hebrew University of Jerusalem, Jerusalem, 91000, Israel
Ikan, R., Department of Organic Chemistry, Natural Products Laboratory, Hebrew University of Jerusalem, Jerusalem, 91000, Israel

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Abstract:

Two new analogues of methyldihydrojasmonate (14); methyl‐2‐oxo‐5‐pentylcyclopentyl‐1‐acetate (5) and methyl‐2‐oxo‐4‐pentylcyclopentyl‐1‐acetate (12) were synthesized. The key step in these syntheses was 1,4‐addition of trialkylborane to α, β‐unsaturated cyclopentenones, 4 and 9. Copyright © 1975 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

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