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Synthesis in Jasmone Series. IV. Preparation of Methyl‐2‐Oxo‐5‐Pentylcyclopentyl‐1‐Acetate and its 4‐Pentyl Analogue
Year:
1975
Source of publication :
Israel Journal of Chemistry
Authors :
Ravid, Uzi
;
.
Volume :
13
Co-Authors:
Ravid, U., Department of Organic Chemistry, Natural Products Laboratory, Hebrew University of Jerusalem, Jerusalem, 91000, Israel
Hoffer, D., Department of Organic Chemistry, Natural Products Laboratory, Hebrew University of Jerusalem, Jerusalem, 91000, Israel
Ikan, R., Department of Organic Chemistry, Natural Products Laboratory, Hebrew University of Jerusalem, Jerusalem, 91000, Israel
Facilitators :
From page:
63
To page:
67
(
Total pages:
5
)
Abstract:
Two new analogues of methyldihydrojasmonate (14); methyl‐2‐oxo‐5‐pentylcyclopentyl‐1‐acetate (5) and methyl‐2‐oxo‐4‐pentylcyclopentyl‐1‐acetate (12) were synthesized. The key step in these syntheses was 1,4‐addition of trialkylborane to α, β‐unsaturated cyclopentenones, 4 and 9. Copyright © 1975 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
Note:
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More details
DOI :
10.1002/ijch.197500008
Article number:
Affiliations:
Database:
Scopus
Publication Type:
article
;
.
Language:
English
Editors' remarks:
ID:
30334
Last updated date:
02/03/2022 17:27
Creation date:
17/04/2018 00:53
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Scientific Publication
Synthesis in Jasmone Series. IV. Preparation of Methyl‐2‐Oxo‐5‐Pentylcyclopentyl‐1‐Acetate and its 4‐Pentyl Analogue
13
Ravid, U., Department of Organic Chemistry, Natural Products Laboratory, Hebrew University of Jerusalem, Jerusalem, 91000, Israel
Hoffer, D., Department of Organic Chemistry, Natural Products Laboratory, Hebrew University of Jerusalem, Jerusalem, 91000, Israel
Ikan, R., Department of Organic Chemistry, Natural Products Laboratory, Hebrew University of Jerusalem, Jerusalem, 91000, Israel
Synthesis in Jasmone Series. IV. Preparation of Methyl‐2‐Oxo‐5‐Pentylcyclopentyl‐1‐Acetate and its 4‐Pentyl Analogue
Two new analogues of methyldihydrojasmonate (14); methyl‐2‐oxo‐5‐pentylcyclopentyl‐1‐acetate (5) and methyl‐2‐oxo‐4‐pentylcyclopentyl‐1‐acetate (12) were synthesized. The key step in these syntheses was 1,4‐addition of trialkylborane to α, β‐unsaturated cyclopentenones, 4 and 9. Copyright © 1975 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
Scientific Publication
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