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Stereoisomers of perhydrophenanthrene. The synthesis and crystal structure of a derivative of the trans-syn-trans isomer
Year:
1984
Source of publication :
Tetrahedron
Authors :
Hönig, Helmut
;
.
Volume :
40
Co-Authors:
Allinger, N.L., Departments of Chemistry, University of Georgia, Athens, GA 30602, U.S.A. and University of Konstanz, Konstanz Federal Republic of Germany
Hönig, H., Departments of Chemistry, University of Georgia, Athens, GA 30602, U.S.A. and University of Konstanz, Konstanz Federal Republic of Germany
Burkert, U., Departments of Chemistry, University of Georgia, Athens, GA 30602, U.S.A. and University of Konstanz, Konstanz Federal Republic of Germany
Asolnai, L., Departments of Chemistry, University of Georgia, Athens, GA 30602, U.S.A. and University of Konstanz, Konstanz Federal Republic of Germany
Huttner, G., Departments of Chemistry, University of Georgia, Athens, GA 30602, U.S.A. and University of Konstanz, Konstanz Federal Republic of Germany
Facilitators :
From page:
3449
To page:
3453
(
Total pages:
5
)
Abstract:
The trans-syn-trans isomer of perhydrohenanthrene has the central ring in a boat conformation. A crystalline derivative (the dibenzoate of the cis 9,10-diol) was prepared, and the crystal structure was determined. The boat conformation is slightly twisted, as predicted by molecular mechanics. © 1984.
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DOI :
10.1016/S0040-4020(01)91495-4
Article number:
Affiliations:
Database:
Scopus
Publication Type:
article
;
.
Language:
English
Editors' remarks:
ID:
18832
Last updated date:
02/03/2022 17:27
Creation date:
16/04/2018 23:24
Scientific Publication
Stereoisomers of perhydrophenanthrene. The synthesis and crystal structure of a derivative of the trans-syn-trans isomer
40
Allinger, N.L., Departments of Chemistry, University of Georgia, Athens, GA 30602, U.S.A. and University of Konstanz, Konstanz Federal Republic of Germany
Hönig, H., Departments of Chemistry, University of Georgia, Athens, GA 30602, U.S.A. and University of Konstanz, Konstanz Federal Republic of Germany
Burkert, U., Departments of Chemistry, University of Georgia, Athens, GA 30602, U.S.A. and University of Konstanz, Konstanz Federal Republic of Germany
Asolnai, L., Departments of Chemistry, University of Georgia, Athens, GA 30602, U.S.A. and University of Konstanz, Konstanz Federal Republic of Germany
Huttner, G., Departments of Chemistry, University of Georgia, Athens, GA 30602, U.S.A. and University of Konstanz, Konstanz Federal Republic of Germany
Stereoisomers of perhydrophenanthrene. The synthesis and crystal structure of a derivative of the trans-syn-trans isomer
The trans-syn-trans isomer of perhydrohenanthrene has the central ring in a boat conformation. A crystalline derivative (the dibenzoate of the cis 9,10-diol) was prepared, and the crystal structure was determined. The boat conformation is slightly twisted, as predicted by molecular mechanics. © 1984.
Scientific Publication
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